Esker
Hero
Power Word Stun is an 8th level spell for a single target stun, only works of targets with 150 HPs or less, and gives a save every round. The spell you wouldn't "certainly wouldn't spend my 6th level slot on" will likely stun for more creature-rounds (since it can catch many), has no HP limit, and is two levels lower.
It grants no save at all in the first round, but also it isn't a good spell for its level. Things you could do instead with a 6th level slot: upcast Hold Monster to two targets that can be up to 180 ft apart, give my melee allies a chance at free crits for however many rounds; or facing a horde upcast animate objects; cast Mass Suggestion on every enemy and get half of them (or however many fail the save) to run away. Yes the first two are concentration, but it's your 6th level slot; something's wrong if it's not your big play of the combat.