It seems like this could be similar to the innate casting from monsters? They can have spells with their innate casting that are not in their regular spell list (the mind flayer is an example).
I could also see a magic user getting that spell and being able to use existing spell slots for it.
For me, a definitive ruling would require knowing how the spell was learned. If it is something innate, I might go with the innate spellcasting route and not allow spell slots to be used. If it is something learned through study, prayer, communing with nature, etc. then I would allow existing spell slots to be used as well. The 1/day becomes a bonus casting at the lowest level. Barring knowledge of how the spell was learned, I would probably lean toward allowing spell slots.
I could also see a magic user getting that spell and being able to use existing spell slots for it.
For me, a definitive ruling would require knowing how the spell was learned. If it is something innate, I might go with the innate spellcasting route and not allow spell slots to be used. If it is something learned through study, prayer, communing with nature, etc. then I would allow existing spell slots to be used as well. The 1/day becomes a bonus casting at the lowest level. Barring knowledge of how the spell was learned, I would probably lean toward allowing spell slots.
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