FFG makes the books I use most aside from the core books.
* Spells & Spellcraft (FFG) - hands down the most used book non-core book I own. I've used the familiar rules, construct rules, spells, This is just a great book.
* Sorcery & Steam (FFG) - yep, its got a broken spine. Cool classes, feats, setting.
* School of Evocation (FFG) - The spells get used a lot.
Also used with some frequency, but not every session
* Familiars (Mongoose Publishing) - The alternate familar paths are really nifty
* Arcane Strife (EN Publishing) - Good resource for Wiz Spells.