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Hmm, does the Elf ability make them automatically know something is there, or just give them a check to notice?

Cost for ammo: Under Masterwork Weapons description. DC: Under Craft Skill.

MW arrows cost 7GP/arrow, or 140GP for a quiver of 20. DC would probably be around 5 for the arrows, and DC 20 to make them masterwork.

So, you can use all 10 charges at one time, but it would take 10 days for it to completely refill? Other than the obvious money this could make, it sounds like a decent idea for a party without healing support.