____________________________________________________Perhaps I've missed it somewhere, but- are there rules established to modify Encounter Levels and/or determine the appropriate CR of a party if it is not a standard four-member party? For example- how would one determine the appropriate encounter for a party consisting of four 2nd-level characters, a third-level character, and a fourth-level character?
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In answer to your 1st question. Yes there are rules for your query. DMG pg 165.
"Determine the party level (average level of the party members)." In your example - 2 x 4 = 8 + 3 + 4 = 15 divide by 6 = 2.5. The rules say you must also round down. Therefore your group's party level is 2. Your party level matches the encounter level.
Next, go to DMG pg 101. "Parties with five or more members can often take on monsters with higher CRs....". After that it doesn't mention any particulars.
Dragon #301 (Dungeoncraft pg 95) answers the rest of your question. It states "There's a rule that says if you double the enemies in an encounter, you increase the EL by +2." "The same sort of rule can apply to PCs". It goes to state for 8 PCs they can handle a challenge of their level +2, 6 PCs would be +1 to the CR/EL, etc.
For your example, the party level would be 2, but they could take on EL3 / CR3 creature.
Hope that helps.