Depends on the High Arcana ability:
Arcane Fire: No, it specifies arcane spells.
Arcane Reach: You sure can. Go ahead and Harm those poor bastards.
Mastery of Counterspelling: You can.
Mastery of Elements: It specifies arcane spells, so no.
Mastery of Shaping: You can. Makes for some rather impressive Flame Strikes, I think.
Spell Power: You can, but if you make it apply to your Cleric or Druid levels, it won't apply to your Wizard levels. Good way to make up for your caster level deficiency, though.
Spell-Like Ability: No, it specifies arcane spells and arcane spell slots.