pawsplay
Hero
Drowbane said:...make the check everytime...
They only have a +33 Concentration. The DC you are looking for is in the neighborhood of 38 (10 + damage dealt), which means there is a 20% chance of the balor failing each time.
A +1 composite longbow (Str +4) with the holy property, using cold iron bane evil outsider arrows, enhanced with a 20th level greater magic weapon to be +5 does an average of 1d6 + 2d6 + 2d6 +11 = 28.5.
The balor's AC is 35. A 20th level Fighter or Ranger with a Dex of 12+ would have at least +27 to hit. With Rapid Shot, you have two attacks at +25, which means each one has a 55% chance of hitting.
Most likely, that balor is not getting his blasphemy off.
That's without the archer having haste, gloves of dexterity, an insane Dex, elemental effects on the bow or the arrows, and an assist from Mordenkainen's Buzzing Bee.