Kid Charlemagne
I am the Very Model of a Modern Moderator
I'd think a rogue would make an excellent choice - all the skill points, the Dex-based skills fit on board ship very nicely, and you could explain away some of his disable device skills as being related to fine jewelry work, or something along those lines.
You could also have a fighter/rogue, with intention of having him take the duellist PrC later on.
You could also have a fighter/rogue, with intention of having him take the duellist PrC later on.