Hirelings were usually overlooked in my experience. I always liked the rules for hiring a gem cutter in the DMG which could improve the value of your gems or ruin them. Pg.30
A weird one that came up when I was looking for rules dealing with blocking movement and such, is that a medium character can be attacked by a maximum of six opponents, and each only through one of the eight cardinal direction (six if using hexes). DMG pg.69
I am sad I've never seen all the rules for collecting eggs or the young of various flying creatures to raise as mounts used in a campaign. Griffon MM pg 50
For that matter, I've never heard of a dragon subdued and then sold. MM pg 30