I had a player actually do that to the hobgoblin common room in Sunless Citadel. They opened the door, saw scores of hobgobs, panicked, then tossed the necklace and slammed the door shut!The Necklace of Missiles (called Necklace of Fireballs in more recent D&Ds) was always a special one. It was like the Staff of the Magi in that you could blow it up in a massive overkill strike. The difference was that there was a plausible chance that you could do so from outside the blast radius. I know several instances where the immediate thing someone did when finding one was to horde it indefinitely for that one perfect occasion to set off all the uses at once -- at a distance-- and let the DM try to figure out how they wanted to do area overflow for multiple fireballs going off at once.
The item was a bribe to induce my buddy's wife to play...