E machines are horrible to upgrade like this (I have owned 3 of them). What you are doing when you change out motherboards and CPU's is building a new computer not upgrading a old one, the motherboard and the CPU are the computer, the other parts are just parts, that being said building a computer is no harder than playing with Legos. Get a case and a new powersupply(don't skimp on the powersupply, I found that out the hard way), alot of cases come with a power supply. Take the old computer completly apart and build the new computer in the new case. You have to do a little research to make sure everything will switch over, I'd advise buying a book or magazine with detailed information on what you are doing (with pictures, you definatly want pictures of each and every step). Another thing to remember is that a simple static electric shock (like you get from dragging your feet over carpet) will completely destroy a motherboard. If you don't feel 100% comfortable with the process then don't do it, you are building a new computer, buying a new computer isn't that expensive anymore.
Links:
http://www6.tomshardware.com/
lots of good information and "how to" articles
http://www.ubid.com/
Yes it is a auction site but it is parts from a company instead of a individual, you can get some pretty good deals there.
http://www.pricewatch.com/
The most important site to check before you buy any component, it can keep you from getting ripped off in just a few clicks of a mouse.
http://www.motherboards.org/
exactly what the title says, they have articles and news on motherboards, very helpful.
http://compgeeks.com/
One of my favorite parts sites, most of the stuff is used or refurbished but you can really save some money here.
http://techsupportalert.com/
lots of how to guides
http://store.yahoo.com/buycaseonline/
huge selection of cases
http://www.electroseller.com/
more cases
http://directron.com/
a huge selection of everything
http://www.tcwo.com/
very good parts site
There are 100's of computer parts sites out there and not all are good ones.