A good character might use an evil means to a good end as a last desperate "My god, what have I done" measure.
A neutral character might use an evil means to a good end when other options are ruled out and think "but at what cost, this victory?"
An evil character aligned with a good goal would use an evil means when convinient with no more than "this act was done for the greater good."
Shoot the hostage? Good guy hesitates trying to find another way, neutral guy says "maybe in the leg" and the evil guy just might have already fired.
Of course, these are all gross simplifications, but the general idea is there.
A neutral character might use an evil means to a good end when other options are ruled out and think "but at what cost, this victory?"
An evil character aligned with a good goal would use an evil means when convinient with no more than "this act was done for the greater good."
Shoot the hostage? Good guy hesitates trying to find another way, neutral guy says "maybe in the leg" and the evil guy just might have already fired.
Of course, these are all gross simplifications, but the general idea is there.