And under the best of circumstances, fighting with two weapons gives you a -2 penalty on weapons wielded in each hand.
The thrown dagger is not "under the best of circumstances", either. Even if he
had the Two Weapon Fighting feat - which he doesn't - it wouldn't reduce the penalty on his thrown dagger.
I am a 1st level human fighter with Point Blank Shot, Rapid Shot, and Quickdraw.
I am face-to-face with an Ork (melee range).
My strength is 14, my dex. 14. I hold a dagger in each hand.
Round starts. I get initiative.
I swing my main hand with the dagger.
Then I swing my off hand with the second dagger.
Then I take a 5' step back and throw a dagger.
What are my bonuses to hit from each of the three (3) attacks?
Okay.
Your BAB is +1, your Dex and Str bonuses are both +2. So your attack bonus is +3 for both melee and ranged.
However, you're using two weapons, with no feats. That's a -6 penalty with your primary hand, and a -10 penalty with your off hand.
Your off hand weapon is light, so those penalties are reduced by 2. But you're using Rapid Shot, so there's another -2 on every attack.
Your primary melee attack, therefore, totals up to -3. Your off hand melee attack totals -7. Your ranged attack is either -3 or -7, depending on which hand you throw with.
On the other hand, if you were a human Ranger with Point Blank Shot and Rapid Shot, plus the Ranger Ambidexterity and Two-Weapon Fighting virtual feats, and the same Str and Dex scores, you would be at :
-1 primary melee.
-1 off-hand melee.
-3 thrown dagger (either hand).
TWF and Ambi make a big difference.
-Hyp.