I think that a bluff check would be in order there.
The opposed charisma check is merely to convince him to do something he ordinarily wouldn't do....the text of the spell states: "An affected creature never obeys suicidal or obviously harmful orders, but it might be convinced that something very dangerous is worth doing."
So I'd make that particular check a bluff check to convince the character that the button is harmless.
So to sum up: Bluff for charmed targets to fool them into doing something suicidal; Charisma check for the moral dilemmas
The opposed charisma check is merely to convince him to do something he ordinarily wouldn't do....the text of the spell states: "An affected creature never obeys suicidal or obviously harmful orders, but it might be convinced that something very dangerous is worth doing."
So I'd make that particular check a bluff check to convince the character that the button is harmless.
So to sum up: Bluff for charmed targets to fool them into doing something suicidal; Charisma check for the moral dilemmas
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