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You can't even use a potion in a grapple without a standard action and concentration check, much less get one from a backpack or pouch.
SRD-Magic Items-Poitions said:Activation: Drinking a potion or applying an oil requires no special skill. The user merely removes the stopper and swallows the potion or smears on the oil. The following rules govern potion and oil use.
Drinking a potion or using an oil on an item of gear is a standard action. The potion or oil takes effect immediately. Using a potion or oil provokes attacks of opportunity. A successful attack (including grappling attacks) against the character forces a Concentration check (as for casting a spell). If the character fails this check, she cannot drink the potion. An enemy may direct an attack of opportunity against the potion or oil container rather than against the character. A successful attack of this sort can destroy the container.
You can't even use a potion in a grapple without a standard action and concentration check, much less get one from a backpack or pouch.