Tiamat CR 30 fiend
Xanathar is a title, and there's been some variation, but current title-holder Zushaxx is a regular beholder CR 13 with a ring of invisibility, ring of resistance, and ring of mind shielding
Mordenkainen hasn't received a full write-up, merely being referred to as an archmage – but if you look at older versions, the character would at least have some cool magic items on top of that.
Tasha is Iggwilv the Witch Queen, a CR 20 fey, according to Wild Beyond the Witchlight. This is a new take or an evolution on the character.