Here's the easy short way to look at it.
Using a scroll draws an AoO just like casting a spell does, except you can't do it defensively.
No other magic item draws an AoO to use, unless the item is involved an action that would normally (ie - without using an item) draw an AoO. For example, if you wore boots that made you run faster...and you ran through a combat...they'd get AoO's. Not because you were wearing the boots, mind, but because you were running within the threatened area of a foe.