Both Expertise and Power Attack, in their description, state that they cannot exceed your BAB. If they cannot do it singly, I would rule as a DM that they certainly cannot do it in tandem.
I look at like this.
Your BAB represents how much skill you have at fighting. Normally all this skill is devoted to attack. With Expertise and PA you can devote that skill to defense or damage, at the expense of your attack. You cannot, however, exceed your level of skill. You are so good, and until you learn more, no better.
If you were a PC in my group, I would rule that your BAB is a pool that can be drawn down to 0, and no further.
However, I am an accomodating fellow. If you really wanted to both Expertise and PA in the same round, after your drew your BAB down to 0, you could start lowering your AC as your fighting style becomes reckless and you leave yourself open to attacks. Obviously, this makes Expertise useless, but you could continue to devote points to PA if you so wished.
<gavel> BANG, BANG!! </gavel>
This court is ajourned.
Irda Ranger
