I'm a big Penny-Arcade and PvP fan, so I really dug the podcast. Having listened to both PA's and Scott Kurtz's podcasts previously, I knew all the voices, but if this is your first listen, it might be a little weird discerning who is who. Especially since they don't do any sort of introduction.
There are alot of really subtle things that made me smile. When Chris uses some obscure word describing the scene, Tycho says, "oooh, I love this guy".
I also wonder if Chris is explaining somethings because it was recorded. Even though Mike is completely new, and Scott hasn't played in ages. I'd really like to see how this progresses.