Caliban said:Funny, it tells me exactly the opposite. It only references acting during combat.
Close. It references not acting during combat. A character who just rolled initiative and is waiting for others to act has not yet acted in combat. He is flat-footed. Just prior to that, during the surprise round and before the character rolled initiative, he has also not yet acted in combat, and is flat-footed. Two hours earlier, when the character was eating breakfast, he had not yet acted in combat. By the bolded text, that makes him flat-footed.
I don't see anything to support the idea you CAN't take immediate actions. Flatfooted means its not your term, but immediate actions can be taken when its not your turn. Hence, you just do it.
I believe the text of Immediate Actions specifically says you can't take them while flat-footed.