I find this to be very helpful-
Source:
Existential Comics. Author: Corey Mohler.
The definition of "food" is not what the Yuan-Ti believes it to be, but what the
player believes it to be- the rules are written for the player, not the character. So, since players don't believe other player characters, while alive, are "food," then since language is use, it follows that Purify Food and Water does not work to cure poison within other player characters.
(You could also do a more advanced reasoning that the more specific rule covers this, and apply canons of construction that would mean that Purify Food and Water would not, but this should suffice. Plus, Wittgenstein!)