Well Sisko became a Q level demigod, so I's say that he qualifies. Hoping that he makes an appearance in the second season of Picard.Doctor Who is a good non-traditional pick.
I am tempted to say names like Captain Jean-Luc Picard or Captain Benjamin Sisko or... Admiral Adama and Captain Apollo. They take risks and always find a way. But of course, they lack superhero costumes and superpowers. Maybe I should pick Data, at least he has superpowers.