I guess this is one of those rare opportunities where publishers can openly campaign for their products without shame.
Well, I'd like to recommend "The Hamlet of Thumble" to you. It is a 72-page adventure setting that includes:
1. a fully detailed hamlet (including stats for nearly 60 NPCs)
2. a short adventure (taking PCs from 1st- to 2nd-level)
3. three core classes (cavalier, shaman, and witch)
4. dozens of spells, feats, and skills
5. rules for reputation points, morale, and improvised weapons
6. tips for a GM (both new and experienced)
And more! You can get more information here:
http://www.openworldpress.com
It was released just a few weeks ago and is already one of the top 20 d20 products of all time, according to EN World:
http://www.enworld.org/reviews/top20.php?p=1&c=print
One reviewer here indeed described it as a "must have" d20 item and it has been selling very well.
Plug over.
I'd also recommend A Magical Medieval Society from Expeditious Retreat Press. There are great adventures from Necromancer Games, Troll Lord Games, Fantasy Flight Games, and Mystic Eye Games that you may want to check out as well.
The best resource is the review section right here at EN World!