A person acts on his beliefs. If someone enjoys fires, but does not act on it and light fires, it's not deep seated enough to be part of his nature(alignment). If the Don orders an arson and he enjoys that fire, it's not because of a chaotic nature. It's just something he enjoys a bit. An actual arsonist is acting on his deeper nature, though. When he enjoys it, it's different than when Joey the Don's Fixer has to light a fire and gets a kick out of it a bit.
Right, your nature needs to be deep enough to cause you to do it anyways for it to count as your nature. That makes zero sense.
Where did you get this. Certainly not from anything I said. A Modron is acting of its own accord on it's lawful nature.
We have to look at what that nature is to determine law/chaos/good/evil/neutral.
An Arsonist acting to his nature is Chaotic, because his nature is to spread Chaos, because he is Chaotic and there fore his Nature is Chaotic.
You see how this is just making circles right? And what if that arsonist who only burns what he is told is by nature chaotic? He just was also employed in a position where following his nature was rewarded. Is he no longer chaotic just because he doesn't try to burn down the entire city? Must Chaos be unmitigated and uncontrolled destruction with no limits?
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Yes.
Family to a devil means the infernal hierarchy of hell, honor means they always keep their word and honor contracts, and tradition (the traditions and customs of hell).
They adhere to a strict caste system, honor contracts, and adhere to tradition.
A Caste system is not Family. The "hierarchy of Hell" is traditionally full of backstabbing and plotting to overthrow each other. That is not family values in any way of the definition.
And while they won't break their word, they are famous for twisting their words and sticking to the letter of what was said. Again, that is not Honor. No one is going to say that a man who sticks to the Letter of his agreements and brutally eviscerates people when he gets the chance (legally) is operating with Honor.
You are stretching these terms way too far.
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I don't know what actions any of these characters are taking that makes you want to assign these particular alignments to them. Also, what's your basis for saying that some of them are more charismatic than others?
Actions?
The Sultan is very much about tradition and law. That is the entire conflict between him and Jasmine, is that the Law states she must be married to a prince.
Aladdin is a thief, a liar, and has zero compunctions about doing whatever it takes to end up where he wants.
Jafar is attempting mind control, magic, ect to take over the kingdom. Wouldn't call him Lawful.
The Sultan is a bit of a bumbler and no one takes him seriously, he has next to zero presence. Sure, he has authority, but that is very different from Charisma. Aladdin has presence galore, he gets Jasmine to fall in love with him nearly by accident, fast talks merchants and guards, and survives on his wits. And Jafar does much the same. he is high in the Sultan's court and has that classic used carsmen charisma and ability to manipulate people.
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Alignment (DnD wise) isnt subjective.
One doesnt find themselves in Celestia on death simply because one genuinely believed themselves to be a lawful and good person.
If you need to die and go to Mount Celestia though to figure out which alingment you are, it isn't terribly useful